Liquid Alkaline Electrolyzer with Concentrated Electrolyte Transport

Application ID: 140291


This tutorial demonstrates how to modify a concentration-independent (also known as a secondary current distribution) liquid alkaline water electrolyzer with concentrated electrolyte theory to explicitly resolve local electrolyte and solvent concentrations (thereby creating a tertiary current distribution). A liquid alkaline electrolyzer is defined in a 2D model with a separator, two gas-electrolyte compartments, and negative hydrogen and positive oxygen electrodes at the boundaries. A stationary solver is used with the cell voltage swept over a range of potentials to generate a polarization curve.

The model is first solved for a secondary current distribution only. Concentrated electrolyte theory is then added and the cell performance is compared between the secondary and tertiary current distribution cases.

This model example illustrates applications of this type that would nominally be built using the following products: