Electrochemical Impedance Spectroscopy
Electrochemical impedance spectroscopy (EIS) is a common technique in electroanalysis. It is used to study the harmonic response of an electrochemical system. A small, sinusoidal variation is applied to the potential at the working electrode, and the resulting current is analyzed in the frequency domain. The real and imaginary components of the impedance give information about the kinetic and ...
Localized Corrosion
Galvanic corrosion between two different phases (alpha and beta phases) in a metallic (magnesium) alloy is simulated for a representative cross-sectional microstructure configuration. A key feature in the model formulation is the implementation of both anodic and cathodic regions at the electrode surface using a single boundary represented in terms of the level set function.
Cyclic Voltammetry at a Macroelectrode in 1D
Cyclic voltammetry is a common analytical technique for investigating electrochemical systems. In this method, the potential difference between a working electrode and a reference electrode is swept linearly in time from a start potential to a vertex potential, and back again. The current-voltage waveform, called a voltammogram, provides information about the reactivity and mass transport ...
Atmospheric Corrosion of a Busbar
This model simulates atmospheric galvanic corrosion of a busbar, which includes a copper flange, an aluminum alloy flange in contact with a zinc nut and bolt. The Secondary Current Distribution interface is used to solve for the electric potential in electrode domain and Current Distribution, Shell interface is used to solve for the electrolyte potential in the thin electrolyte layer. The ...
Cathodic Protection of Steel in Reinforced Concrete
This example models cathodic protection of a steel reinforcing bar in concrete. Three different electrochemical reactions are considered on the steel surface. Charge and oxygen transport are modeled in the concrete domain, where the electrolyte conductivity and oxygen diffusivity depend on the moisture content. The impact of different moisture levels on the corrosion currents is investigated.
Galvanic Corrosion with Electrode Deformation
This 2D model demonstrates how to model a galvanic couple in which the corrosion of the anode causes a geometry deformation. The parameter data used is for an Magnesium Alloy (AE44) - mild steel couple in brine solution (salt water).
Carbon Dioxide Corrosion in Steel Pipes
Carbon dioxide in aqueous solution is highly corrosive and can cause significant damage to steel designs. Such conditions arise in pipes used in a variety of applications, especially within the petrochemical industry. In this tutorial example, turbulent flows consisting of carbon dioxide and water corrode the steel surface of pipes. The corrosion is influenced by the temperature and pH. This ...
Ship Hull ICCP
Impressed current cathodic protection is a commonly employed strategy to mitigate the ship hull corrosion where an external current is applied to the hull surface, polarizing it to a lower potential. In this model, the effect of propeller coating on the current demand is demonstrated.
Corrosion Protection of an Oil Platform Using Sacrificial Anodes
Steel structures immersed in seawater can be protected from corrosion through cathodic protection. This protection can be achieved by an impressed external current or by using sacrificial anodes. The use of sacrificial anodes is often preferred due to its simplicity. This example models the primary current distribution of a corrosion protection system of an oil platform using sacrificial ...
Galvanized Nail
This tutorial example serves as an introduction to the Corrosion Module and models the metal oxidation and oxygen reduction current densities on the surface of a galvanized nail, surrounded by a piece of wet wood, which acts as electrolyte. The protecting zinc layer on the nail is not fully covering, so that at the tip of the nail the underlaying iron surface is exposed. First the electrolyte ...